A high voltage is applied across a gap between a sample solution and an electrode, forming a plasma that directly samples the solution and produces atomic emission that is used to identify and quantify the solution's elemental constituents. The solution-cathode glow discharge (SCGD) is a simplified and improved version of the electrolyte-cathode glow discharge. Two glow discharges, both operated at atmospheric pressure to improve desolvation, are described and characterized here. Traditionally, glow discharges have found little use in the analysis of solutions, largely due to their inefficiency in vaporizing the solvent. This document describes a new method, making use of pulsed GD and monochromatic imaging, that adds lateral resolution better than 100 µm. However, it has historically lacked lateral (in the plane of the sample surface) resolution.
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Glow discharge has predominately been used for the analysis of solids, and it offers high sensitivity and depth resolution at a comparatively low cost in this application. The methods described here seek to improve upon areas where GD falls short of other methods and to exploit the areas where GD excels, particularly speed and cost. Glow discharge (GD) is a flexible and potent platform from which to develop new spectrochemical methods, including those for elemental analysis.
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Opportunities exist for new instruments that strike a different balance from existing methods, particularly if these new techniques offer advantages over existing ones. Sensitivity, accuracy, precision, portability, expense, sample size, speed, and other aspects of analysis are balanced based on the nature of a problem and the available resources. Powerful instrumentation exists for the determination of elemental concentrations in a range of samples, but all such instruments are the product of compromises among desirable properties.